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QUESTION PAPER

2024 BOARD EXAM

CBSE CLASS 12-PCM CHEMISTRY Board Paper 2024 — Set 3

2024

CHEMISTRY

CLASS 12-PCM

CBSE EXAMINATION PAPER-2024 CHEMISTRY

CBSE EXAMINATION PAPER-2024

CHEMISTRY

(Solved)

Time allowed : 3 hours

Maximum Marks : 17

General Instructions :

Read the following instructions carefully and follow them :

  1. This question paper contains 15 questions. All questions are compulsory.
  2. This question paper is divided into 4 sections.
  3. Section A – questions number 1 to 4 are case based questions
  4. Section B – questions number 5 to 11 are multiple choice questions
  5. Section C – questions number 12 to 13 are very short answer
  6. Section D – questions number 14 to 15 are short answer
  7. There is no overall choice given in the question paper. However, an internal choice has been provided in few questions.
  8. Use of calculator is NOT allowed.

Section A

Question 1. The involvement of (n-1)d electrons in the behaviour of transition elements impart certain distinct characteristics to these elements. Thus, in addition to variable oxidation states, they exhibit paramagnetic behaviour, catalytic properties and tendency for the formation of coloured ions. The transition metals react with a number of non-metals like oxygen, nitrogen and halogens. KMnO4 and K2Cr2O7 are common examples. The two series of inner transition elements, lanthanoids and actinoids, constitute the f-block of the periodic table. In the lanthanoids, there is regular decrease in atomic size with increase in atomic number due to the imperfect shielding effect of 4f-orbital electrons which causes contraction.
Question 2.

The involvement of (n 1)d electrons in the behaviour of transition elements impart certain distinct characteristics to these elements. Thus, in addition to variable oxidation states, they exhibit paramagnetic behaviour, catalytic properties and tendency for the formation of coloured ions. The transition metals react with a number of non-metals like oxygen, nitrogen and halogens. KMnO 4 examples. and K 2 Cr 2 O 7 are common The two series of inner transition elements, lanthanoids and actinoids, constitute the f-block of the periodic table. In the lanthanoids, there is regular decrease in atomic size with increase in atomic number due to the imperfect shielding effect of 4f-orbital electrons which causes contraction. Answer the following questions :

Question 3.

The involvement of (n 1)d electrons in the behaviour of transition elements impart certain distinct characteristics to these elements. Thus, in addition to variable oxidation states, they exhibit paramagnetic behaviour, catalytic properties and tendency for the formation of coloured ions. The transition metals react with a number of non-metals like oxygen, nitrogen and halogens. KMnO 4 examples. and K 2 Cr 2 O 7 are common The two series of inner transition elements, lanthanoids and actinoids, constitute the f-block of the periodic table. In the lanthanoids, there is regular decrease in atomic size with increase in atomic number due to the imperfect shielding effect of 4f-orbital electrons which causes contraction. Answer the following questions :

Question 4.

The involvement of (n 1)d electrons in the behaviour of transition elements impart certain distinct characteristics to these elements. Thus, in addition to variable oxidation states, they exhibit paramagnetic behaviour, catalytic properties and tendency for the formation of coloured ions. The transition metals react with a number of non-metals like oxygen, nitrogen and halogens. KMnO 4 examples. and K 2 Cr 2 O 7 are common The two series of inner transition elements, lanthanoids and actinoids, constitute the f-block of the periodic table. In the lanthanoids, there is regular decrease in atomic size with increase in atomic number due to the imperfect shielding effect of 4f-orbital electrons which causes contraction. Answer the following questions :

Section B

Question 5.

Which of the following does not show variable oxidation states?

[1 Marks]
  • (A) Cu
  • (B) Mn
  • (C) Sc
  • (D) Fe
Question 6.

(CH₃)₂CH-O-CH₃ when treated with HI gives:

[1 Marks]
  • (A) (CH₃)₂CH - OH + CH₃ -I
  • (B) (CH₃)₂CH -I + CH₃OH
  • (C) (CH₃)₂CH -I + CH₃ -I
  • (D) (CH₃)₂CH - OH + CH₃OH
Question 7.

Which of the following compounds on treatment with benzene sulphonyl chloride forms an alkali-soluble precipitate?

[1 Marks]
  • (A) CH₃CONH₂
  • (B) (CH₃)₃N
  • (C) (CH₃)₂NH
  • (D) CH₃CH₂NH₂
Question 8.

The order of increasing basicities of CH₃NH₂ (I), (CH₃)₂NH (II), (CH₃)₃N (III) and C₆H₅NH₂ (IV) in aqueous media is:

[1 Marks]
  • (A) IV < III < I < II
  • (B) I < II < III < IV
  • (C) II < III < I < IV
  • (D) II < I < IV < III
Question 9.

The vitamin which plays an important role in coagulating blood is:

[1 Marks]
  • (A) Vitamin A
  • (B) Vitamin E
  • (C) Vitamin D
  • (D) Vitamin K
Question 10.

When a catalyst increases the rate of a chemical reaction, then the rate constant (k):

[1 Marks]
  • (A) may increase or decrease depending on the order of the reaction
  • (B) increases
  • (C) remains constant
  • (D) decreases
Question 11.

During the electrolysis of aqueous NaCl, the cathodic reaction is:

[1 Marks]
  • (A) Oxidation of H₂O
  • (B) Reduction of H₂O
  • (C) Oxidation of Cl⁻ ion
  • (D) Reduction of Na⁺ ion

Section C

Question 12. Define molal depression constant. How is it related to enthalpy of fusion?
[2 Marks]
Question 13.

What type of deviation is shown by ethanol and acetone mixture? Give reason.What type of azeotropic mixture is formed by that deviation ?

[2 Marks]

Section D

Question 14.

A solution is prepared by dissolving 5 g of a non-volatile solute in 200 g of water. It has a vapour pressure of 31·84 mm Hg at 300 K. Calculate the molar mass of the solute.

(Vapour pressure of pure water at 300 K = 32 mm Hg)

[3 Marks]
Question 15.

A first-order reaction is 25 complete in 40 minutes. Calculate the value of rate constant. In what time will the reaction be 80 % complete ?

Given : log 2 = 0·30, log 3 = 0·48, log 4 = 0·60, log 5 = 0·69

[3 Marks]

Paper Details

CBSE Board Exam 2024

Class

CLASS 12-PCM

Subject

CHEMISTRY

Year

2024

Set

Set 3

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