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QUESTION PAPER

2024 BOARD EXAM

CBSE CLASS 12-PCM CHEMISTRY Board Paper 2024 — Set 1

2024

CHEMISTRY

CLASS 12-PCM

CBSE EXAMINATION PAPER-2024 CHEMISTRY

CBSE EXAMINATION PAPER-2024

CHEMISTRY

(Solved)

Time allowed : 3 hours

Maximum Marks : 18

General Instructions :

Read the following instructions carefully and follow them :

  1. This question paper contains 29 questions. All questions are compulsory.
  2. This question paper is divided into 3 sections.
  3. Section A – questions number 1 to 13 are case based questions
  4. Section B – questions number 14 to 27 are multiple choice questions
  5. Section C – questions number 28 to 29 are very short answer
  6. There is no overall choice given in the question paper. However, an internal choice has been provided in few questions.
  7. Use of calculator is NOT allowed.

Section A

Question 1. Batteries and fuel cells are very useful forms of galvanic cell. Any battery or cell that we use as a source of electrical energy is basically a galvanic cell. However, for a battery to be of practical use it should be reasonably light, compact and its voltage should not vary appreciably during its use. There are mainly two types of batteries: primary batteries and secondary batteries. In the primary batteries, the reaction occurs only once and after use over a period of time the battery becomes dead and cannot be reused again, whereas the secondary batteries are rechargeable. Production of electricity by thermal plants is not a very efficient method and is a major source of pollution. To solve this problem, galvanic cells are designed in such a way that energy of combustion of fuels is directly converted into electrical energy, and these are known as fuel cells. One such fuel cell was used in the Apollo space programme.
Question 2.

Batteries and fuel cells are very useful forms of galvanic cell. Any battery or cell that we use as a source of electrical energy is basically a galvanic cell. However, for a battery to be of practical use it should be reasonably light, compact and its voltage should not vary appreciably during its use. There are mainly two types of batteries secondary batteries. primary batteries and In the primary batteries, the reaction occurs only once and after use over a period of time the battery becomes dead and cannot be reused again, whereas the secondary batteries are rechargeable. Production of electricity by thermal plants is not a very efficient method and is a major source of pollution. To solve this problem, galvanic cells are designed in such a way that energy of combustion of fuels is directly converted into electrical energy, and these are known as fuel cells. One such fuel cell was used in the Apollo space programme.

Answer the following questions :

Question 3.
Question 4.
Question 5.
Question 6.
Question 7.
Question 8.

Question 9.

Batteries and fuel cells are very useful forms of galvanic cell. Any battery or cell that we use as a source of electrical energy is basically a galvanic cell. However, for a battery to be of practical use it should be reasonably light, compact and its voltage should not vary appreciably during its use. There are mainly two types of batteries secondary batteries. primary batteries and In the primary batteries, the reaction occurs only once and after use over a period of time the battery becomes dead and cannot be reused again, whereas the secondary batteries are rechargeable. Production of electricity by thermal plants is not a very efficient method and is a major source of pollution. To solve this problem, galvanic cells are designed in such a way that energy of combustion of fuels is directly converted into electrical energy, and these are known as fuel cells. One such fuel cell was used in the Apollo space programme. Answer the following questions :

Question 10.

Batteries and fuel cells are very useful forms of galvanic cell. Any battery or cell that we use as a source of electrical energy is basically a galvanic cell. However, for a battery to be of practical use it should be reasonably light, compact and its voltage should not vary appreciably during its use. There are mainly two types of batteries secondary batteries. primary batteries and In the primary batteries, the reaction occurs only once and after use over a period of time the battery becomes dead and cannot be reused again, whereas the secondary batteries are rechargeable. Production of electricity by thermal plants is not a very efficient method and is a major source of pollution. To solve this problem, galvanic cells are designed in such a way that energy of combustion of fuels is directly converted into electrical energy, and these are known as fuel cells. One such fuel cell was used in the Apollo space programme. Answer the following questions :

Question 11.

Batteries and fuel cells are very useful forms of galvanic cell. Any battery or cell that we use as a source of electrical energy is basically a galvanic cell. However, for a battery to be of practical use it should be reasonably light, compact and its voltage should not vary appreciably during its use. There are mainly two types of batteries secondary batteries. primary batteries and In the primary batteries, the reaction occurs only once and after use over a period of time the battery becomes dead and cannot be reused again, whereas the secondary batteries are rechargeable. Production of electricity by thermal plants is not a very efficient method and is a major source of pollution. To solve this problem, galvanic cells are designed in such a way that energy of combustion of fuels is directly converted into electrical energy, and these are known as fuel cells. One such fuel cell was used in the Apollo space programme. Answer the following questions :

Question 12.

Batteries and fuel cells are very useful forms of galvanic cell. Any battery or cell that we use as a source of electrical energy is basically a galvanic cell. However, for a battery to be of practical use it should be reasonably light, compact and its voltage should not vary appreciably during its use. There are mainly two types of batteries secondary batteries. primary batteries and In the primary batteries, the reaction occurs only once and after use over a period of time the battery becomes dead and cannot be reused again, whereas the secondary batteries are rechargeable. Production of electricity by thermal plants is not a very efficient method and is a major source of pollution. To solve this problem, galvanic cells are designed in such a way that energy of combustion of fuels is directly converted into electrical energy, and these are known as fuel cells. One such fuel cell was used in the Apollo space programme. Answer the following questions :

Question 13. Batteries and fuel cells are very useful forms of galvanic cell. Any battery or cell that we use as a source of electrical energy is basically a galvanic cell. However, for a battery to be of practical use it should be reasonably light, compact and its voltage should not vary appreciably during its use. There are mainly two types of batteries secondary batteries. primary batteries and In the primary batteries, the reaction occurs only once and after use over a period of time the battery becomes dead and cannot be reused again, whereas the secondary batteries are rechargeable. Production of electricity by thermal plants is not a very efficient method and is a major source of pollution. To solve this problem, galvanic cells are designed in such a way that energy of combustion of fuels is directly converted into electrical energy, and these are known as fuel cells. One such fuel cell was used in the Apollo space programme.

Section B

Question 14.

Which one of the following first row transition elements is expected to have the highest third ionization enthalpy ?

[1 Marks]
  • (A) Manganese (Z = 25)
  • (B) Vanadium (Z = 23)
  • (C) Chromium (Z = 24)
  • (D) Iron (Z = 26)
Question 15.

Two among the three components of DNA are β-D-2-deoxyribose and a heterocyclic base. The third component is :

[1 Marks]
  • (A) Phosphoric acid
  • (B) Adenine
  • (C) Sulphuric acid
  • (D) Uracil
Question 16.

For an electrolyte undergoing association in a solvent, the vant factor :

[1 Marks]
  • (A) has negative value
  • (B) has zero value
  • (C) is always greater than one
  • (D) is always less than one
Question 17.

For the reaction X + 2Y → P, the differential form equation of the rate law is :

[1 Marks]
  • (A) -d[P]/dt = -d[X]/dt
  • (B) -2d[Y]/dt = +d[P]/dt
  • (C) 2d[P]/dt = -d[Y]/dt
  • (D) +d[X]/dt =-d[P]/dt
Question 18.

Acetic acid reacts with PCl₅ to give :

[1 Marks]
  • (A) CCl₃ -COOH
  • (B) Cl -CH₂ -COOH
  • (C) Cl -CH₂ -COCl
  • (D) CH₃- COCl
Question 19.

The formation of cyanohydrin from an aldehyde is an example of :

[1 Marks]
  • (A) nucleophilic addition
  • (B) electrophilic addition
  • (C) electrophilic substitution
  • (D) nucleophilic substitution
Question 20.

The reaction of an alkyl halide with sodium alkoxide forming ether is known as :

[1 Marks]
  • (A) Reimer-Tiemann reaction
  • (B) Williamson synthesis
  • (C) Kolbe reaction
  • (D) Wurtz reaction
Question 21.

The correct order of the ease of dehydration of the following alcohols by the action of conc. H₂SO₄ is :

[1 Marks]
  • (A) (CH₃)₂CH- OH > (CH₃)₃C- OH > CH₃CH₂- OH
  • (B) (CH₃)₂CH- OH > CH₃CH₂- OH > (CH₃)₃C- OH
  • (C) CH₃CH₂ -OH > (CH₃)₂CH- OH > (CH₃)₃C -OH
  • (D) (CH₃)₃C- OH > (CH₃)₂CH- OH > CH₃CH₂- OH
Question 22.

Which functional groups of glucose interact to form cyclic hemiacetal leading to pyranose structure ?

[1 Marks]
  • (A) Ketone group and hydroxyl group at C- 4
  • (B) Aldehyde group and hydroxyl group at C- 4
  • (C) Ketone group and hydroxyl group at C- 5
  • (D) Aldehyde group and hydroxyl group at C- 5
Question 23.

Assertion (A) : When NaCl is added to water a depression in freezing point is observed.

Reason (R) : NaCl undergoes dissociation in water.

[1 Marks]
  • (A) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
  • (B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
  • (C) Assertion (A) is false, but Reason (R) is true.
  • (D) Assertion (A) is true, but Reason (R) is false.
Question 24.

Assertion (A) : Separation of Zr and Hf is difficult.

Reason (R) : Zr and Hf have similar radii due to lanthanoid contraction.

[1 Marks]
  • (A) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
  • (B) Assertion (A) is true, but Reason (R) is false.
  • (C) Assertion (A) is false, but Reason (R) is true.
  • (D) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
Question 25.

Assertion (A) : The pKₐ of ethanoic acid is lower than that of Cl -CH₂- COOH.

Reason (R) : Chlorine shows electron withdrawing ( I) effect which increases the acidic character of Cl -CH 2- COOH.

[1 Marks]
  • (A) Assertion (A) is false, but Reason (R) is true.
  • (B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
  • (C) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
  • (D) Assertion (A) is true, but Reason (R) is false.
Question 26.

Assertion (A) : Aniline is a stronger base than ammonia.

Reason (R) : The unshared electron pair on nitrogen atom in aniline becomes less available for protonation due to resonance.

[1 Marks]
  • (A) Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
  • (B) Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
  • (C) Assertion (A) is true, but Reason (R) is false.
  • (D) Assertion (A) is false, but Reason (R) is true.
Question 27.

Which of the following compounds will give a ketone on oxidation with chromic anhydride (CrO₃) ?

[1 Marks]
  • (A) CH₃ -CH₂ -CH (OH)-CH₃
  • (B) (CH₃)₃C- OH
  • (C) CH3CH2CH2OH
  • (D) (CH3)2CH -CH2OH

Section C

Question 28.

Calculate the potential of Iron electrode in which the concentration of

Fe2+ ion is 0·01 M.

(E°Fe2+/Fe = 0·45 V at 298 K)

[Given : log 10 = 1]

[2 Marks]
Question 29.

Define molecularity of the reaction. State any one condition in which a bimolecular reaction may be kinetically of first order

[2 Marks]

Paper Details

CBSE Board Exam 2024

Class

CLASS 12-PCM

Subject

CHEMISTRY

Year

2024

Set

Set 1

Other Years — CHEMISTRY

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2022 Set-2

2022 Set-3

2022 Set-4

2022 Set-5

2023 Set-1

2023 Set-2

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2024 Set-1

2024 Set-2

2024 Set-3

2024 Set-4

2024 Set-5

2025 Set-1

2025 Set-2

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